Tuning effect of silicon substitution on magnetic and high frequency electromagnetic properties of R2Fe17 and their composites

In this work, we report the tuning effect of the Si substitution on the magnetic and high frequency electromagnetic properties of R₂Fe₁₇ compounds and their paraffin composites. It is found that the introduction of Si can remarkably improve the magnetic and electromagnetic properties of the R₂Fe₁₇ compounds, making the R₂Fe_17–xSi_x-paraffin composites excellent microwave absorption materials (MAMs). By introducing the Si element, their saturation magnetizations decrease slightly, while much higher Curie temperatures are obtained. Furthermore, better impedance match is reached due to the decrease of the high-frequency permittivity ε′ by about 40%–50%, which finally enhances the performance of the microwave absorption. The peak frequency (f_RL) of the reflection loss (RL) curve moves toward high frequency domain and the qualified bandwidth (QB, RL ≤ ?10 dB) increases remarkably. The maximum QB of 3.3 GHz (12.0–15.3 GHz) is obtained for the Sm_1.5Y_0.5Fe₁₅Si₂-paraffin composite (d = 1.0 mm) and the maximum RL of ?53.6 dB is achieved for Nd₂Fe₁₅Si₂-paraffin composite (d = 2.2 mm), both surpassing most of the reported MAMs. Additionally, a distinguished dielectric microwave absorption peak is observed, which further increases the QB in these composites.     

具有双通道数据包丢失的Delta算子系统故障检测

研究同时存在双通道数据包丢失和时变时延的Delta算子网络控制系统（NCSs）故障检测问题.假定数据包丢失发生在控制器到执行器、传感器至控制器的数据传输过程中，并且利用两个相互独立的伯努利随机变量描述是否发生丢包.将上述的NCSs建模为网络切换系统，提出任意切换律下故障检测滤波器的设计方法.利用线性矩阵不等式（LMIs）方法、Lyapunov-Krasovskii泛函和平均驻留时间等得出所考虑的网络切换系统具备指数均方稳定性的充分条件.证明了所用的网络切换系统满足H_∞性能，并推导出了滤波器参数的显式表达.数值仿真结果验证了所提方法的有效性.     

Femtocell网络的鲁棒议价博弈功率控制

针对具有不完美信道状态信息的Femtocell双层网络，为了保证网络效用最大化、最小服务质量要求及Femtocell用户之间的效用公平，提出了基于议价博弈的鲁棒功率控制方案.在保证宏小区用户正常传输情况下，考虑到Femtocell家庭用户的最小服务质量要求，将Femtocell网络的鲁棒功率控制问题转化为议价博弈功率控制问题.为了保证Femtocell家庭用户之间的公平性，给出了Kalai-Smorodinsky（K-S）议价博弈解，证明了议价博弈解的存在性和唯一性，并提出了一种基于二分查找算法的分布式鲁棒功率控制方案.仿真结果表明，所提出的算法不仅具有较好的收敛性能，而且能够较好地保证用户之间的公平性.     

热力学分析MnS夹杂物析出与控制

 为了深入研究与控制重轨钢中大尺寸MnS夹杂物,针对目前热力学计算MnS析出行为问题,提出在应用时需要根据实际条件做相应的选择进行计算。在比较了目前几个常用的热力学数据后,基于U75V钢中MnS夹杂物形成过程,建立了适合计算MnS夹杂物析出的分段计算方法。研究表明,采用FactSage 6.4商业软件计算MnS析出温度为1 631 K,与平衡热力学参数计算的结果1 694 K相差63 K。该方法可准确预测MnS的析出行为,降低了热力学分析MnS析出的难度。在1 473、1 573 和1 673 K 3个温度下固溶硫质量分数分别为0.000 67%、0.001 67%和0.010 8%。在铸坯轧制之前的开坯和保温温度为1 563 K时,需要将钢中硫质量分数降低到0.001 67%以下,才能有效控制大尺寸的MnS夹杂物。     

Can lanthanum doping enhance catalytic performance of silver in direct propylene epoxidation over NaMoAg/SiO_2?

In the attempt to reduce surface free energy of silica to improve interaction of silica with silver, silica was doped by different amounts of low surface energy lanthanum, La_2O_3, through impregnation. The doped and undoped silica were used as supports for preparation of Na/Ag/Mo/La_2O_3-SiO_2 catalysts. Catalytic performances of the catalysts were evaluated in direct epoxidation of propylene(DPO) using molecular oxygen under atmospheric pressure and without adding hydrogen. Adding 5 wt%La to the Na/Ag/Mo/SiO_2 catalyst improves both the catalysts electivity in DPO and its stability over 20h of time-on-stream.The characterization results show that La_2O_3 species interact strongly with silver particles on the silica surface which result in significant improvement in the dispersion profile of silver and marked decrease in the size of silver nanoparticles(AgNPs). The estimated mean diameter of AgNPs is ca. 4.0 nm in Na/Ag/Mo/5 wt%La_2O_3-SiO_2, which is smaller than that(53.9 nm) found in Na/Ag/SiO_2. The presence of subnanometer AgNPs on Ag/La_2O_3-SiO_2 prior addition of MoO_3 and NaCl to the sample can enhance the mutual electronic synergism between Ag, MoO_3 and Na for selective production of propylene oxide.     

Water chemistry,solution resistivity,and oxygen reduction reaction in simulated primary coolant of pressurized water reactors

The effect of temperature (25 °C–300 °C) on the ohmic potential drop (ΔE_Ω) and resistivity (R_sol) of a simulated primary coolant of the pressurized water reactors was investigated using electrochemical impedance spectroscopy (EIS) and galvanostatic potentiometry. The variations in the conductivity and pH of the solution showed that by increasing the temperature the magnitude of the R_sol and therefore ΔE_Ω of the system first decreases rapidly (until ~150 °C) and then reaches a relatively stable plateau value. Increasing the pressure of the system decreased the magnitude of the R_sol in the oxygenated coolant. Investigation of the oxygen reduction reaction (ORR) on platinum (Pt), 316L stainless steel (SS), Alloy 690, and carbon steel revealed the great effect of water chemistry, in particular pH on the rate of the ORR on these materials. OH^? adsorption on Pt reduced the rate of the ORR on this metal at temperatures higher than ~100 °C. Finally, it was found that higher H₃O⁺ concentrations reduce the rate of the ORR on iron‐ and nickel‐based alloys, while increasing the OH^? concentration at temperatures higher than ~150 °C accelerates the rate of the ORR on these alloys.     

基于Kӧtter方程的盾构掘进面上被切削土体受力研究

为了计算不同土体性质与不同掘进参数下盾构刮刀与土体之间的作用力以及由此带来的切削扭矩,引入了修正后的Kӧtter方程作为补充方程,求解出开挖面上土体在被动切削至破坏时滑动面上的应力分布,建立了被切削土体受力模型,求解出刮刀刃面与土体之间的正压力p、摩擦力Q与侧向土体间抗剪阻力U,进而推导出刀盘切削扭矩T的计算公式。分析得到特定刀盘上刮刀的p,Q,U值随土体c,φ值增大而增大,通过适当提高刮刀刃面粗糙度来增大摩擦可使土体更易被切至破坏;p,Q,U值随刀盘转速ω增大而减小,p,Q随支护荷载p线性增大且p对于被切削土体受力的影响在砂性土中较大,最终给出特定刀盘掘进至部分种类土体中的切削扭矩值作为工程参考。     

LTE系统多小区上行联合功控算法

针对传统的小区内开环功率控制算法通常以提升本小区的吞吐量性能为目标，忽略了当前小区用户对邻小区用户同频干扰的问题，为提升边缘用户性能的同时兼顾系统整体性能，提出了一种LTE系统小区间上行联合功率控制（UJPC）算法。该算法采用单基站三扇区为系统模型，以最优化系统吞吐量比例公平函数为目标，首先根据最小信干噪比（SINR）约束值和用户最大发射功率这两个约束条件得到相应的数学优化模型，然后采用连续凸近似的方法求解优化问题得出各个基站所管辖的小区内所有用户的最优发射功率。仿真结果表明，与基准的开环功控方案相比，联合功控方案在保证系统平均频谱利用率的情况下能够较大幅度地提高小区边缘频谱利用率，其最佳性能增益能达到50%。     

固体自拉曼激光器多波长输出研究

实验对比了a切和c切的Nd∶YVO4晶体作为激光晶体时,激光器输出光光谱及输出功率上的区别。设计了一种小型化固体自拉曼多波长激光器,实验证明通过调节倍频晶体BBO的角度,可实现多波长选择性输出及同时输出,并测量了其输出光谱及单波长输出时的功率。     

Dual closed-loops current controller for a 4-leg shunt APF based on repetitive control

ABSTRACT

Current repetitive control strategy for a 4-leg APF is usually of a poor speed in responding to the drastic changes in load harmonic profile. In this paper, a dual closed-loop current controller composed of a repetitive control-based outer loop and a PI-based inner loop is proposed to improve the performance of a 4-leg APF, with a focus on response speed and harmonic current compensation gain. The principle of the dual loop controller is explained in detail, and the stability of the system is analysed thoroughly. To further decrease the inherent time delay associated with the PWM strategy, a zero-sequence-voltage-based PWM strategy is proposed to solve the complexity in the implementation of 3D-SVPWM methods. By formulating the relationship between the duty ratio of the neutral leg control pulse and the zero-sequence-component of the reference voltages, the duty ratios of the other three legs can be calculated conveniently. The simulation and lab experiment results are provided to verify the correctness and effectiveness of the proposed dual closed-loop current controller and the zero-sequence-voltage-based PWM strategy.